Preheat Oven & Pan:
Place a sheet pan in the oven and preheat to 425°F (220°C).
Prepare Chicken:
In a large bowl, toss chicken with vegetable oil. In a small bowl, combine cornstarch, salt, and pepper. Sprinkle over chicken and toss to coat.
Make Sauce:
In a medium bowl, whisk together rice vinegar, brown sugar, ketchup, soy sauce, pineapple juice, and garlic. In a small bowl, stir cornstarch and water into a slurry, then whisk into sauce.
Arrange Ingredients:
Carefully remove the hot sheet pan. Spread chicken in a single layer with space between pieces. Scatter bell peppers, onion, and pineapple evenly around the chicken.
First Bake:
Drizzle half the sauce over the pan. Bake for 15 minutes.
Glaze & Finish:
Remove pan, flip chicken pieces, stir vegetables, and pour remaining sauce over everything. Bake an additional 10 minutes, or until chicken reaches 165°F (74°C) and sauce is sticky.
Garnish & Serve:
Sprinkle with sliced green onions and sesame seeds. Serve immediately.